Nanjing Liwei Chemical Co., Ltd

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Bismuth Chloride: Breaking Down the Facts and Prospects

Historical Development

Looking back at the story of bismuth chloride, it’s clear that curiosity has always fueled progress. Back in the early 18th century, chemists puzzled over new elements, and bismuth was no exception. Plenty of confusion surrounded its difference from lead and tin, but by the mid-1700s, Carl Wilhelm Scheele managed to tease out its true identity. Moving ahead, French and German scientists experimented with hydrochloric acid and elemental bismuth, resulting in what we now call bismuth trichloride. Through conflicts and industrial shifts, demand waxed and waned. Even so, the age of analytical chemistry cemented the compound’s place, as its unique reactions and use as a reagent made it essential for labs, especially during the surge of 19th-century science. The world wars drove deeper searches for specialty chemicals, pulling bismuth chloride into metallurgical trials and pigment production. Each decade pushed its purification, turning a curious laboratory result into a more refined substance.

Product Overview

Bismuth chloride steps into the ring as a pale yellow solid or powder, easy to spot if you’ve ever worked around inorganic chemistry. Its chemical formula—BiCl3—makes it clear this isn’t some run-of-the-mill salt. Often used in research and niche manufacturing, many companies offer technical and high-purity versions, catering to differences in purity and moisture content. Solid at room temperature, it easily dissolves in most polar solvents. Laboratories keep it on hand for a diverse set of projects, ranging from catalyst creation to pigment testing, making bismuth chloride a frequent flyer in experimental chemical recipes.

Physical & Chemical Properties

As a compound, bismuth chloride shows real character. It shows up as a green-yellow powder or, when pure, almost white crystals. Anyone handling it quickly notices its low melting point of about 227 degrees Celsius and its tendency to form steamy hydrochloric acid fumes when heated or mixed with water. Its density checks in at roughly 4.75 grams per cubic centimeter, heavier than most organic materials in the lab. It dissolves easily in hydrochloric acid but prefers staying clear of water, which triggers hydrolysis and turns it into bismuth oxychloride and hydrochloric acid gas. In dry air, the crystals keep their gloss but, in damp conditions, they'll chalk up fast. Its low volatility and strong reactivity with reducing agents also mean strict storage and handling facilities aren’t just a preference—they’re a must for anyone working with sizable quantities.

Technical Specifications & Labeling

Suppliers selling to industry and research updates their technical data sheets regularly, but certain numbers rarely shift. The compound usually comes in at 99% or higher purity for lab needs. Moisture must stay below 0.5%, since unwanted water triggers partial hydrolysis and changes the chemical makeup. Granular or powder forms get packed in amber glass or sealed PE bottles, with lot numbers and production dates stamped for traceability. Labels highlight bismuth content as well as the expected chloride ratio, giving clear indicators for anyone double-checking compatibility. Some sector regulations call for barcodes with digital batch tables tied to local inventory software, helping manage recalls or checks in case impurities show up downstream.

Preparation Method

Smelting and halide chemistry form the backbone of bismuth chloride production. Starting from pure bismuth metal, producers drill down with hot chlorine gas or drip concentrated hydrochloric acid over heated bismuth billets. A steady exothermic reaction cracks open the metal and bonds up chloride ions. Another common approach uses a reaction between bismuth(III) oxide and concentrated hydrochloric acid, a route that offers better control over yield and avoids handling toxic elemental chlorine. Each step gets closely monitored, as side reactions like oxychloride formation lurk if anyone rushes reagent addition or misses a temperature swing. Once formed, manufacturers wash, dry, and sometimes perform second-stage purification to keep out trace sulfur, iron, or lead. Those contaminants skew downstream reactions and show up under modern analytical testing, so even small labs keep a close eye on preparation procedures.

Chemical Reactions & Modifications

Bismuth chloride doesn’t just sit on a shelf. Its main claim to fame comes through its interactions with water, alkalis, and organic ligands. Drop a fresh sample in water and hydrolysis sets in, producing white bismuth oxychloride precipitate—a favorite for cosmetics and pigments. Add strong reducing agents, and the chloride sheds ions, leaving behind elemental bismuth that can be isolated further. Organic chemists value it as a mild Lewis acid catalyst in Friedel–Crafts-type reactions, giving new tools for molecule assembly. Halide exchange with potassium bromide or iodide swaps out chloride ions, producing heavier bismuth halides on demand. Double metal salt formations with copper, zinc, or iron build bridge compounds that often find roles in advanced synthesis or sensor work. Each new modification makes bismuth chloride more adaptable for custom research pathways and specialty chemical processes.

Synonyms & Product Names

Shopping for bismuth chloride calls for a short memory for synonyms. Names like bismuth trichloride, bismuth(III) chloride, and tribismuth trichloride commonly appear. Catalogues in Europe and Asia list it as chlorure de bismuth or cloruro de bismuto, while older references might call it butter of bismuth. CAS number 7787-60-2 shows up on most labels, making cross-brand checks easier. Trade names don’t vary much in English, but certain specialty reagent suppliers brand premium batches with their own abbreviations or suffixes for purity and granule size.

Safety & Operational Standards

Handling bismuth chloride means keeping things orderly. Skin and respiratory exposure create real risk, since fumes generated during hydrolysis release hydrochloric acid, a strong irritant. Labs and factories stick to strict practices: gloves, face shields, fume hoods, and sealed containers for any step involving open powder. MSDS documentation recommends prompt hand washing and immediate eyewash station use if splashes happen. Storage works best below 25 degrees Celsius and well away from moisture sources. Air-tight containers and silica gel packs slow down hydrolysis, keeping material fresh. Waste from preparation or use never goes straight down the sink; disposal runs through regulated hazardous waste streams, usually picked up by chemical handling outfits with licenses for halide-bearing metals. Emergency protocols call for rapid room evacuation in case of larger spills, backed up by chemical neutralization kits. OSHA and European REACH guidelines set the bar for most businesses and keep employees trained and prepared for potential leaks or exposures.

Application Area

Cosmetic companies turn to bismuth chloride’s conversion product, bismuth oxychloride, for that smooth, pearly look in pressed powders and eyeshadow. Analytical chemists add it as a standard for chloride detection or in gravimetric assays tracing heavy metals. Electronics researchers take advantage of its reactivity to create conductive inks or low-melting solders, shrinking the footprint of wearable electronic prototypes. As a Lewis acid, it drives certain organic couplings, especially where classic catalysts fall short. Metalworking outfits sometimes add it to plater baths or minor alloys for improved texture and appearance. Specialty glassmakers and ceramics developers explore its use for color shifts and as an opacifier in batch trials. Paint and pigment designers value it for the crystal finish delivered by its oxychloride form. Emerging application fields in environmental testing and battery research keep shifting, spurred by bismuth chloride’s increasingly visible profile as a safer and less toxic alternative to lead-based compounds.

Research & Development

Modern R&D pushes bismuth chloride in new directions. Labs look for greener routes to synthesis, reducing both byproducts and workplace hazards. New surface coating techniques use the compound’s tendency to hydrolyze, creating nano-structured surfaces for advanced optics and sensor projects. Organometallic chemists experiment with bismuth chloride as a precursor for building larger, more elaborate clusters, drawing on bismuth’s unique size and electron structure. Teams running high-throughput screening for photovoltaic materials sometimes plug bismuth chloride into vapor phase and thin film processes, tracking performance versus legacy ingredients. Across all these ventures, cross-disciplinary collaboration defines the tempo, and digital analysis of trace contaminants makes current research faster and more accurate than ever. Each year, conferences bring new updates on catalyst improvements, environmental releases, and cutting-edge medical applications emerging from ongoing studies into the compound’s behaviors and breakdown pathways.

Toxicity Research

Studies dating back to the 1940s rarely found urgent toxicity threats for bismuth chloride in low doses, but larger exposures or breakdown in wet environments ramp up concerns, mostly tied to hydrochloric acid production. Researchers catalog adverse reactions: skin and eye irritation, respiratory distress, and organ-specific concerns after repeated exposure or ingestion. Animal studies link high levels to kidney and liver damage, though humans exposed through cosmetic products rarely absorb enough to see problems. The move away from lead and mercury has thrown more attention to bismuth salts as safer options, but modern labs still run ongoing research on accumulation in aquatic species and soil environments. Some clinical research explores links between chronic bismuth exposure and nervous system changes, but results remain mixed, driving continued medical follow-up. As detection limits keep dropping and regulatory standards rise, new protocols aim to keep exposure low for both consumers and workers.

Future Prospects

Industry buzz points to several new frontiers for bismuth chloride. In pigment development, the push keeps going for longer-lasting, non-toxic colorants, and this compound sits at the core of those efforts. Electrochemistry teams look to insert it into battery and fuel cell components, targeting cleaner and safer energy storage. Additive manufacturing startups experiment with bismuth chloride blends in specialty 3D printing filaments for electronics and medical devices. With global pressures to eliminate hazardous heavy metals, manufacturers are turning to bismuth-based alternatives, giving this compound new opportunities in coatings and electronics. Policy changes in Europe and North America favor less hazardous substance handling, so more research dollars flow toward refining production processes that dump fewer wastes and demand less energy. Analysts tracking the chemical industry forecast a steadily growing market, especially as more companies test and adopt green chemistry protocols making bismuth chloride a keystone ingredient for years to come.



What is Bismuth Chloride used for?

Everyday Chemistry and Reliable Results

Bismuth chloride doesn’t make the front page, but this compound earns a quiet respect in labs and factories. It shows up in places many folks never expect. If you step into a chemistry lab, you might spot a small container labeled “BiCl3”. Chemistry students remember it for its yellowish-white color and strong reaction to water. Here’s a compound that reacts in surprising, useful ways.

Supporting Organic Synthesis

Bismuth chloride makes the wheels turn in many organic syntheses. Chemists reach for it to speed up reactions, especially when making building blocks for pharmaceuticals or dyes. Instead of relying on heavy metals that damage health and the planet, many labs appreciate how bismuth compounds offer lower toxicity. This means less risk in handling and fewer headaches for anyone aiming to meet safety standards like REACH in Europe.

Pharmaceutical Applications

Search for treatments against stomach ulcers or digestive issues and you’ll come across bismuth-based drugs. Older remedies like bismuth subsalicylate grab most of the attention. That said, making these drugs means starting with reagents such as bismuth chloride. By controlling how the compound reacts, manufacturers deliver safe and effective products. Bismuth’s low absorption in the human body helps avoid toxic side effects. That kind of reliability gives patients and doctors peace of mind, especially compared to outdated therapies with rougher impacts.

Diagnostics and Research

Beyond treatments, bismuth chloride lends a hand behind the scenes. Lab technicians use it to test proteins and organic molecules. I’ve watched researchers run “spot tests” where a simple drop tells them whether a vital compound like urea is present. Bismuth chloride brings out visible reactions, such as color changes, that tell a clear story. In some university courses, these reactions are part of practical exams, helping instructors know students learned the basics. Reliable, visible markers cut confusion in the lab.

Material Science: Coatings and Electronics

Looking past medicines, bismuth chloride has a spot in the world of materials science. If you open up the hood on some electronic circuits, you’ll see tiny connections made with alloys containing bismuth. Sometimes, these alloys come from chemical routes that use bismuth chloride as a starter. These electronics run cooler than those using lead, cutting down on device failures and environmental harm. Even in coatings and glasses, bismuth compounds bring surprisingly effective properties, like increased refractive index or non-toxic pigmentation.

Environment and Sustainability

As sustainability gets more attention, chemists lean toward ingredients with less impact. Bismuth chloride offers an edge because it breaks down into non-hazardous forms more readily than compounds with heavy metals like cadmium or lead. In my own circles, manufacturers talk about the importance of switching away from toxic chemicals. When regulations loom overhead, bismuth-based processes often line up as alternatives folks can pitch to regulators and communities. Responsible end-of-life disposal also sits easier with bismuth compounds, which helps companies avoid fines and public criticism.

Room to Improve

Every compound can cause concern in the wrong hands. Handling bismuth chloride shouldn’t mean ignoring best practices. Folks need good ventilation, eye protection, and protective gloves—basic gear for anyone working with reactive chemicals. Storage far from moisture keeps surprises to a minimum. As the chemical industry evolves, firms might invest more in alternatives and safer handling protocols. But for now, bismuth chloride occupies a useful, reliable spot in chemical production, research, and health-care supply chains.

What is the chemical formula of Bismuth Chloride?

Getting to Know the Chemical Formula

Bismuth chloride catches the eye of chemists and students because of its formula: BiCl3. It might look simple, but those three chlorine atoms attached to one bismuth atom play a big role in how this compound behaves. The arrangement stems from the common oxidation state of bismuth, which is +3. This matches up with the three -1 charges from the chloride ions, making the formula make sense from an electron-sharing point of view. My early days in the lab showed how easily a small change in the formula could lead to big changes in a compound’s color, solubility, and use. BiCl3 stands as a great example of this delicate chemistry dance.

Where Bismuth Chloride Shows Up

Bismuth chloride isn’t just for shelf display in a chemistry classroom. Industrial and research chemists lean on this compound for its properties. You’ll see BiCl3 show up in synthesizing other bismuth compounds and in organic chemistry laboratories, especially when a mild Lewis acid comes in handy. In pharmaceuticals, some research teams look at bismuth’s unique behavior, since it combines some heavy metal qualities with relative safety compared to other elements in its family. Even in the past, bismuth compounds played roles in cosmetics and pigment production, giving an edge to certain products that needed stability and safety.

Looking Closer at the Science

Hard science backs up the formula. Bismuth, found in group 15 of the periodic table, is heavier than lead but far less toxic. Chlorine brings high electronegativity, stealing electrons from bismuth and locking into a stable arrangement. These bonds make BiCl3 fairly stable as a solid, but water quickly cracks it apart, releasing hydrochloric acid and turning the bismuth into bismuth oxychloride. I remember watching this textbook demonstration in college—nothing replaces seeing the chalky white oxychloride form right in front of you. It drives home how sensitive transition metal halides can be to water, something that pushes chemists to think ahead about storage and handling.

Factoring In Health and Environmental Footprints

Bismuth chloride takes a different path than most heavy metal salts. Lead and mercury get their own warning stickers, with bismuth showing noticeably milder side effects. The numbers from toxicology studies back this up. Although not something to handle carelessly, bismuth salts generally land on the safe end of the spectrum, giving them a slight preference in processes seeking less hazardous chemicals. The environmental side tells a similar story. As more teams look to replace high-risk substances, the choice of bismuth compounds grows, even if the mining and purification of bismuth still leave a mark.

Building Toward Safer Use and Alternatives

In the hunt for progress, communication and training help cut down on mistakes. Students and lab techs learn early to check chemicals twice, store them in dry spots, and use proper gloves. For bigger processes, switching old school lead or mercury salts out for bismuth ones leads to fewer headaches about pollution and workplace exposure. The job doesn’t end there. Recycling spent bismuth salts and exploring by-products for additional use could lower costs and waste. As new research shines a light on alternatives and green chemistry takes off, bismuth chloride keeps its spot as both a useful tool and a stepping stone toward even safer practices in chemistry.

Is Bismuth Chloride toxic or hazardous?

What Bismuth Chloride Brings to the Table

Bismuth chloride, a compound with the formula BiCl3, pops up in chemical labs, industry, and research. It often plays the role of a catalyst or reagent, especially when trying to get certain reactions to move along. On the surface, bismuth sits far from lead and mercury on that old hazard list. Many people see it as a safer cousin to heavier metals. Pharmacies even use pure bismuth for upset stomachs. The trouble starts with the “chloride” end of the equation and how bismuth turns up in different forms.

How Hazardous Is Bismuth Chloride?

I’ve seen people treat bismuth chloride with the same trust they’d give table salt. That’s a mistake. It eats away at moisture, pulling water right out of the air. Water—on skin, eyes, or inside a bottle—turns it acidic. Splash a little on your hand, and you’re dealing with a substance that can sting, cause redness, or worse. I’ve watched powders puff out of containers during lazy handling, and that can lead to trouble in the lungs or throat if you breathe it in. Heated bismuth chloride spits out hydrochloric acid gas, which brings big irritation and lung damage if you’re unlucky enough to inhale it.

Fact-Checking the Risks

The Centers for Disease Control and Prevention (CDC) lists bismuth chloride as an irritant. The National Institute for Occupational Safety and Health (NIOSH) puts bismuth chloride hazards between harsh acids and the milder salts. Chloride ions create risks for burns, so even though bismuth acts a little gentler, the compound won’t let users toss aside goggles or gloves. Wastewater or accidental spills bring environmental questions. Bismuth won’t poison rivers the way mercury or cadmium might, but aquatic toxicity studies showed that runoff from chloride-heavy solutions can stunt or kill small organisms in test habitats. That tells me “safe” doesn’t always mean “harmless.”

Lessons Learned in Real-Life Labs

I remember my first encounter with bismuth chloride. A tiny splash from opening a bottle left a brief burning itch, a sharp reminder that no one should underestimate chemicals, no matter their reputation. College students run into the stuff and walk out thinking it’s as safe as table sugar. A few minutes of exposure can give a false sense of security, but one bad spill or forgotten glove brings a dose of reality. In workplaces, I’ve seen protocols slip—open containers by hand in open rooms, pour powders without a mask, ignore splashes on the counter. People slow down and pay attention only after a close call.

Paths Toward Safer Use

Clear habits make all the difference. Simple protective gear—gloves, goggles, and a lab coat—blocks most accidents. Fume hoods, though sometimes skipped for the sake of “quick” tasks, help stop vapors from reaching lungs or drifting through a room. Containers should stay tightly closed, since this chemical drinks up water and spills from moist air. For storage, well-labeled bottles and dry, ventilated shelves keep dangers at arm’s length. After use, collect and neutralize waste instead of dumping it down the drain. Training students and workers to respect chemicals, not just memorize procedures, builds a culture where accidents shrink.

Looking Beyond the Label

Bismuth chloride may not be as famous—or notorious—as some heavy metal salts, but ignoring risks just leads to mishaps. Science leans on experience, and a little caution goes a long way. That’s what keeps labs cleaner, workers safer, and the environment a bit healthier.

How should Bismuth Chloride be stored?

The Risks Behind Careless Storage

Bismuth chloride, a pale yellow compound, grabs attention in the lab with its unique chemical properties. A few years ago, I managed an inventory in a college lab known for its rotating crowd of researchers. Bismuth chloride showed up on our shelf, and not everyone respected its quirks. Once, a jar stood too close to a busy sink, and someone forgot to tighten the lid. Within a week, we discovered the compound had clumped, picking up moisture from the air. Poor storage not only wasted money, but also posed a serious safety concern.

Bismuth chloride reacts with water and humid air, releasing hydrochloric acid gas. Anyone who’s ever inhaled even a little of that sharp, choking vapor remembers the sting. Improper handling endangers everyone. If dust or vapors escape, they pose a threat to lungs and skin. It's not enough to tuck the container away. Solid procedures protect the people working with these chemicals, and relying on proper handling builds a safe lab environment for the future.

Choosing the Right Container

Any direct contact with air spells trouble for this compound. Thick glass containers stand up against corrosion and keep fumes from leaking. Polyethylene and similar plastics often break down when exposed to chemicals like bismuth chloride, so glass remains the wise choice. Secure the lid tightly to limit exposure. Wide-mouthed jars might seem handy, but narrow necks cut down on accidental spills and lower the chance of moisture sneaking in during use.

Environment Makes the Difference

Room temperature storage only works if the space stays dry and cool. Humidity speeds up decomposition, making the compound cake or break apart. The storeroom should never double as a hot, sticky backroom or be near a sink. Desiccators, which pull moisture out of the air using drying agents like silica gel, trap bismuth chloride away from humidity. Even a clear storage policy, visible on the cabinet or shared in group meetings, keeps everyone honest about safe practice.

Label for Safety and Clarity

Too many labs skip the basics and end up with mystery jars. Labels on bismuth chloride should stick out: use bold writing for the chemical name, hazard warnings, and the date it came in. I've seen expired labels save a team from a near miss, especially with compounds that slowly decompose or change appearance. If you have to transfer contents, write the whole set of warnings again. Poison control, safety precincts, and regulatory bodies want clear, unmistakable markings.

Handling Spills and Waste

Chloride compounds cause headaches quickly if a container breaks. Simple steps count for a lot. Spilled material needs swift cleanup without spreading dust through the air. Use a dustpan, wet rags, and seal everything in a bag marked "chemical waste." Never dump it down the drain. Seal broken containers and contact proper disposal crews. I learned early on: shortcuts invite long-term damage or injuries. Everyone wants a safe cleanup, not a disaster story for next year's orientation.

Building Safer Habits

Bismuth chloride doesn't demand fear, just respect. Safe storage—dry, sealed, and labeled—keeps everyone out of trouble. Talk about it, check on it, and make storage part of daily routine. It only takes a few thoughtful actions to protect lives, budgets, and scientific results. If more people follow these habits, labs stay safer and smarter for the scientists who arrive next year—and the ones after that.

What are the physical properties of Bismuth Chloride?

What Stands Out with Bismuth Chloride?

Bismuth chloride grabs attention even before anyone gets to the lab. Look at it closely—the stuff catches the eye as a pale yellow to white powder or crystals, depending on the light and humidity in the room. If you've ever handled the compound, you’ll remember its fragile look. Touch it, and the powder has a slightly oily texture, not gritty or rough. Its color sometimes deepens if left out, pointing to its reaction with air moisture.

Melting, Boiling, and Breaking Down

Many researchers remember the first time melting bismuth chloride. It doesn’t take a blast furnace, just some careful heating. Around 227 degrees Celsius, it melts, forming a light yellow liquid. That's not a particularly high melting point for a metal halide. Bump up the temperature to 447°C, and it boils. This sharp transition is one reason scientists pay attention to it during synthesis—things can go from solid to vapor quickly, which pushes you to keep an eye on the thermometer.

Solubility and Reactions with Water

Drop bismuth chloride into water, you’ll notice it doesn’t dissolve cleanly. It reacts almost instantly with water, forming bismuth oxychloride and hydrochloric acid. This leaves a white, cloudy suspension. That look of milky water after adding the powder makes it apparent something’s going on, and reminds us that chemistry isn’t always about clear solutions. This feature means labs often use other solvents like hydrochloric acid or ether. Bismuth chloride dissolves well in those, so finding the right solvent matters.

Odor, Taste, Density, and Other Physical Traits

There’s nothing strong about its smell. If you’ve ever smelled dry office paper, imagine something even less. The taste is not for trying—bismuth chloride isn’t safe to eat and can irritate the mouth and stomach. It’s denser than water, about 4.7 grams per cubic centimeter, so even a small pile weighs more than it looks.

Appearance and Storage

One thing that stands out for those who spend hours in the chemical storeroom: bismuth chloride needs a dry, tightly sealed bottle. Its tendency to pull in moisture and break down means sloppy storage quickly leads to ruined stocks. The crumbly, yellow crystals turn into a useless, white mass if exposed to air for too long. Keeping it in an airtight glass container, away from dampness, matters more than many realize.

Why the Physical Side Really Matters

Real labs seldom work with perfect conditions, and bismuth chloride’s physical side shapes every experiment and every batch prepared in industry. If you want a smooth reaction, keep it dry and avoid water contamination. The powder’s tendency to clump if left open slows things down, wastes time, and causes inconsistent results. Each of these features—melting point, solubility troubles, air sensitivity—means every chemist using it learns in a hurry how to handle and store it. Students, professionals, and anyone serious about getting the chemistry right find themselves talking about these physical quirks more often than the textbook theoreticals.

Redefining Practical Chemistry

Having spent time rooting around with many inorganic compounds, bismuth chloride always stands out as a test of preparation skills. It’s as much about practical knowledge as it is about chemical curiosity. Those willing to respect these basic physical facts, from humidity control to temperature awareness, avoid headaches and wasted supplies. Understanding its physical fingerprint shapes both daily routines and the larger process of discovery.

Bismuth Chloride
Bismuth Chloride
Bismuth Chloride
Names
Preferred IUPAC name Trichlorobismuthane
Other names Bismuth(III) chloride
Bismuth trichloride
Bismuth chloride (BiCl3)
Pronunciation /ˈbɪzməθ ˈklɔːraɪd/
Identifiers
CAS Number 7787-60-2
Beilstein Reference 3588500
ChEBI CHEBI:30163
ChEMBL CHEMBL1201568
ChemSpider 21542533
DrugBank DB11161
ECHA InfoCard 100.029.168
EC Number 232-116-4
Gmelin Reference 2120
KEGG C06445
MeSH D001677
PubChem CID 24763
RTECS number EK2975000
UNII AI78502000
UN number 2476
Properties
Chemical formula BiCl3
Molar mass 315.34 g/mol
Appearance White or pale yellow crystalline solid
Odor Odorless
Density Density: 4.7 g/cm³
Solubility in water 8.5 g/100 mL (20 °C)
log P -0.6
Vapor pressure Negligible
Acidity (pKa) -1.00
Basicity (pKb) -0.1
Magnetic susceptibility (χ) −219.6×10⁻⁶ cm³/mol
Refractive index (nD) 2.03
Dipole moment 2.65 D
Thermochemistry
Std molar entropy (S⦵298) 191.9 J·mol⁻¹·K⁻¹
Std enthalpy of formation (ΔfH⦵298) -377 kJ/mol
Pharmacology
ATC code A01AB06
Hazards
Main hazards Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
GHS labelling GHS02, GHS07
Pictograms GHS07
Signal word Warning
Hazard statements H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
Precautionary statements P280, P305+P351+P338, P337+P313
NFPA 704 (fire diamond) 1-0-2-W
Lethal dose or concentration LD₅₀ oral (rat): 1,500 mg/kg
LD50 (median dose) LD50 (median dose): Oral rat LD50 = 500 mg/kg
NIOSH BQ6475000
PEL (Permissible) PEL (Permissible Exposure Limit) for Bismuth Chloride: Not Established
REL (Recommended) 24 months
Related compounds
Related compounds Bismuth oxychloride
Bismuth(III) fluoride
Bismuth(III) bromide
Bismuth(III) iodide