Nanjing Liwei Chemical Co., Ltd

Знание

Copper Acetate Monohydrate: More Than Just a Lab Chemical

Historical Development

Copper Acetate Monohydrate has been kicking around since the days of alchemists, who saw it as a sign of transformation. In medieval times, folks used it in pigment-making for vibrant greens and blues, known as verdigris, giving famous frescoes their signature look. Chemists in the 18th and 19th centuries refined its preparation and began to document its reactions more carefully. By the early 1900s, industry started to rely on it for producing fungicides and catalysts, particularly in textile and dyeing processes. Through the 20th century, new uses in electronics and organic synthesis kept expanding, embedding copper acetate monohydrate deeply into industrial and scientific routines.

Product Overview

Copper Acetate Monohydrate comes as striking blue-green crystals. Because it dissolves readily in water and ethanol, it grabs a place on the shelves of chemical labs, research centers, and factories. You see it in handy containers with moisture protection, since it easily absorbs water from the air. In the real world, it's not just tucked away for scholarly experiments. I’ve seen it at work in agriculture, protecting plants from fungal attacks, and in pigments for art restoration, helping to match that specific historic hue. Thanks to its reliability, it pops up across an unusually wide set of applications—proof that utility can trump obscurity for even the strangest-sounding chemicals.

Physical & Chemical Properties

This compound earns its reputation for being a copper salt that speaks through color and reactivity. Its blue-green appearance, caused by copper ions, stands out on the shelf and makes it easy to identify, even for those with only a little chemistry training. With a molecular formula of Cu(CH3COO)2·H2O, it weighs in at about 199.65 g/mol. In the lab, it melts around 115°C and loses its water molecule at low heat. It dissolves nicely in water and alcohol, which explains why it moves so effectively in solution-based processes. You get a slight vinegar smell, which tips you off to the acetate part—never pleasant, but memorable. Chemically, it swings between being a Lewis acid and a mild oxidizing agent, setting up all sorts of interactions when mixed with organic or inorganic materials.

Technical Specifications & Labeling

Reputable suppliers specify purity up to 99%, sometimes a notch lower for bulk or technical uses. Labels always spell out the proper chemical name, molecular formula, and concentration. Storage details highlight a cool, dry spot, as this chemical drinks up moisture if left open. You’ll commonly spot hazard communication elements—pictograms, precautionary statements—mandated by regulations for safe handling. Every shipment includes the CAS number, batch tracking, and a certificate of analysis, responding to strict traceability expectations demanded by pharmaceutical, agricultural, and scientific users alike.

Preparation Method

Copper Acetate Monohydrate arises from a direct reaction between copper(II) oxide or copper carbonate and acetic acid, with heat speeding things along. As the copper dissolves, beautiful blue-green crystals begin to separate out when the solution cools. Filtering and recrystallization follow, guaranteeing purity and keeping unwanted copper salts at bay. Traditionally, the equipment’s nothing fancy—glass beakers, filter paper, and patient stirring do the trick just as well as any modern reactor for small batches. Scaling up means closed systems and careful control of concentration, keeping dust and moisture in check.

Chemical Reactions & Modifications

In the right hands, copper acetate monohydrate’s chemistry opens up. The copper(II) ion can exchange with other ligands, creating a string of new compounds for specialized tasks. Drop it into organic reactions, and you get oxidative coupling, giving a boost to complex molecule synthesis. Replace the acetate with other carboxylates, and a whole family of copper-based catalysts for polymerization, oxidation, or cross-coupling steps emerges. The monohydrate’s water of crystallization can be driven off, shifting the crystal structure and changing reactivity. In small-scale art or restoration chemistry, heating it just enough to tweak properties without breaking it down can actually restore faded colors unfamiliar to modern pigments.

Synonyms & Product Names

People call this compound by a few names: copper(II) acetate monohydrate, cupric acetate monohydrate, and blue verdigris are all common. In commerce, companies may list it as cupric acetate, even though true cupric acetate technically lacks water of hydration. Older literature might refer to it as crystalline verdigris or simply copper acetate, but a careful researcher checks the full chemical name and formula before making a purchase, mindful of historic naming quirks that sometimes lead to confusion, especially when reading archives or ordering from global suppliers.

Safety & Operational Standards

Anyone handling copper acetate monohydrate owes it respect. Getting it on your skin can leave an itchy rash, and inhaling dust shouldn’t ever be an option—lab masks and gloves turn into everyday safeguards. Swallowing it triggers nausea and more severe copper toxicity if exposure runs long. Storage in sealed containers, marked with hazard symbols, keeps the chemical from spreading where it shouldn’t. Waste protocols require clearly marked bins and strict separation from incompatible materials, like strong acids or bases, which can lead to hazardous reactions. Training staff on spill clean-up, first aid, and emergency procedures forms a front line of defense, making those rules mean something, not just occupy space in a binder.

Application Area

Copper acetate monohydrate shows up wherever copper’s distinct touch is needed. In agriculture, it acts as a fungicide for vineyards, tackling mold before it ruins the season. Textile factories use it to dye fabrics, coaxing out sharp greens and blues. In the chemical industry, this compound steps up as a reagent for coupling and oxidation, linking molecules that refuse to react on their own. Education and research call on it for classroom demonstrations or lab analysis, introducing students to the world of transition metal chemistry. Electronic manufacturing takes advantage of its predictable reactivity when growing copper-based thin films for circuit boards and sensors. The pigment and restoration world still counts on it for creating hues that modern synthetic dyes can’t quite match.

Research & Development

Research labs investigate copper acetate monohydrate as a building block for new catalysts that push reactions to greater efficiency and sustainability. I’ve read studies where scientists tweak the reaction conditions to lower waste output or up the selectivity in organic synthesis—helping cut down on byproducts that require expensive purification later. Nanotechnology groups use it to craft copper-based nanosheets or nanoparticles for next-generation batteries and electronic devices, aiming to bridge the gap between small-scale demonstration and real-world application. In environmental chemistry, new work tests this compound for breaking down persistent organic pollutants and easing the cleanup of industrial waste, giving this long-used chemical a fresh relevance in the age of sustainability.

Toxicity Research

Smart handling of copper acetate monohydrate depends on understanding its effects on health and the environment. Research papers document how even small exposure over time can cause copper buildup in the liver and kidneys, especially in people with pre-existing health issues. Ecotoxicity studies measure its mild risk to aquatic life if waste enters the water stream, making careful disposal not just a regulatory box to tick but a shared responsibility. To reduce health risks, the best workplaces push for closed reaction systems, real-time exposure monitoring, and routine health checks. Industry groups track new findings, tweaking safety data sheets as new risks show up in published journals or field experience.

Future Prospects

The chemistry field always hunts for higher performance, cleaner processes, and better materials, giving copper acetate monohydrate plenty of room to shine. Cutting-edge battery designs and new catalytic cycles continue drawing on its copper core for innovation. Environmental chemists see it as a stepping stone to metal-organic frameworks and green solvents that shrink the environmental impact. Paired with artificial intelligence, automated labs tune copper acetate’s chemistry for faster, smarter results, handing down process improvements that ripple through manufacturing and research. The push to recycle critical elements and the boom in electronic waste recovery highlight copper compounds as both a challenge and a tool for cleaner technologies. With each new breakthrough, copper acetate monohydrate remains a familiar but flexible partner—adaptive in the hands of those who understand both its history and its promise.



What is Copper Acetate Monohydrate used for?

Not Just Blue Crystals in a Jar

Copper acetate monohydrate lives in the shadow of everyday metals like iron and aluminum, yet it shows up in places far away from where most folks expect. Its brilliant blue color catches the eye, though its real value often hides in invisible reactions inside labs, fields, and factories. Early in my work with experimental chemistry, I found it tucked away on a storeroom shelf, dusty from lack of use, only to realize it had punched above its weight in organic synthesis and industrial processing for years.

The Role in Chemistry and Experimentation

In the world of research and education, copper acetate monohydrate helps chemists move reactions forward. It nudges molecules to form new bonds or helps break them apart in ways that speed up discovery. My university years saw it play a supporting role in oxidation reactions, where it handed off its copper ions, helped turn alcohols into ketones, and added backbone to key classroom experiments. You notice pretty quickly how it delivers consistent, reliable change—one batch to the next.

A Partner in Making Pigments and Dyes

Walk through an artist’s supply store or tour a historic restoration site, and chances are, copper acetate played a role behind the scenes. In making pigments like verdigris (the greenish-blue color beloved by painters centuries ago), copper acetate lends its signature blue hues to other, more complex shades. Art conservators still value traditional chemistry, where copper solutions bring out colors on aged wood and stone. Even pesticides took shape with this same compound back in the day—fungicides for grapevines and fruit trees, with Bordeaux mixture carrying copper acetate as a proven weapon against blights.

Electroplating and Industrial Work

Beyond paint and paper, copper acetate assists in plating metals. Its easy dissolvability in water and ability to deliver copper ions makes it handy in laying a thin copper coat on circuit boards or decorative metals. Factories and workshops trust this technique to keep costs down and quality up. I once visited a small electronics shop where workers dipped circuit boards into baths of blue-green solution—copper acetate at work, building connections that would allow a phone or radio to work.

Laboratory Value and Learning

In classrooms, copper acetate monohydrate continues to serve as a teaching tool for new chemists. Its clear blue color and reliable reactions demonstrate foundational lessons in coordination chemistry, crystal formation, and color change. Beyond simple demonstrations, lab instructors often refer to it for qualitative analysis, where it reveals the presence of other elements in a sample. Its big advantage rests in its predictable behavior, which helps students understand how chemical reactions move from plan to result.

Risks and Responsible Use

Every compound with potential comes with risk. Exposure to copper acetate can cause health issues if mishandled—skin or eye contact, inhalation, or accidental swallowing could provoke problems. Safe handling and storage, proper gloves and goggles, and clear instructions all matter in keeping people safe. Industry and academia have pushed health and safety standards to reduce risks, but awareness remains key.

Looking Ahead: Smarter Applications

With pressures on agriculture, electronics, and manufacturing, copper chemistry keeps adapting. Scientists already search for more sustainable, less hazardous alternatives and tighter recycling within industrial chains. Even so, copper acetate monohydrate stays in rotation thanks to its reliability, affordability, and versatility. Its story continues, not just as a pretty crystal in a glass jar, but as an ingredient that helps projects move from experiment table to real-world solution.

What is the chemical formula of Copper Acetate Monohydrate?

Chemistry You See Everywhere

Copper acetate monohydrate has the formula Cu(CH3COO)2·H2O. A single copper ion binds with two acetate ions, and a water molecule tags along for the ride. You’ll run across this blue-green crystal in college labs and maybe you’ve seen it stained on a filter paper while learning about double displacement reactions.

Plenty of people think chemistry only lives in textbooks. This compound shows up in real-life settings. Folks use it as a fungicide in vineyards and gardens, where it helps defend crops from mold and mildew. Sometimes, it's handy during organic synthesis in research labs. It can act as a reagent for oxidation reactions, giving students and scientists practical results. And for those who enjoy mineral collecting or home experiments, crystals of copper acetate monohydrate turn out strikingly blue-green—easy to spot and fun to grow.

Why Details Like Chemical Formulas Matter

Chemical formulas don’t just help chemists. Clear formulas prevent confusion. If the label lists Cu(CH3COO)2·H2O, you know you’re dealing with monohydrate, not the anhydrous form. These small differences matter. Water trapped in the crystal changes mass, reactivity, and even how a compound handles in the air.

Getting hands dirty in a lab taught me this. Using the wrong hydrate throws off calculations. Suddenly, your measurements are off, and results start looking strange. Once, while preparing a solution, I ignored the “monohydrate” part and the outcome didn't add up. Details like “·H2O” impact everything from yield to results in titration, right down to how a powder clumps together during storage.

Quality, Safety, and Environmental Factors

Anyone handling chemicals deserves clear information. Students, teachers, and farmers all rely on trustworthy labels and instructions. If a bag’s label skips over the exact formula, mistakes follow—sometimes with serious consequences. Misidentifying compounds like copper acetate monohydrate has led to contamination in soil or over-application in crops, which can harm ecosystems and people.

Recent studies from agricultural agencies underline the importance of following directions on these copper-based compounds. Too much can build up in soil, damaging helpful microorganisms. Responsible use and correct identification keep fields healthy and water sources clean. Environmental impact reports from Europe and the US Environmental Protection Agency both highlight proper dosing and storage as crucial, and that always starts with a sharp eye for what’s on the container.

Solutions Rooted in Careful Practice

People teach chemistry to sharpen attention to detail for good reason. Having accurate labels, using checklists before starting work, and double-checking the formulas help prevent small errors from growing into big problems. More schools and supply companies moving to clear digital databases help ensure anyone from students to professionals can confirm they’re holding Cu(CH3COO)2·H2O, and not something else entirely.

By sharing best practices and insisting on transparent information, communities cut down on accidents and make science accessible at every level. The everyday habit of reading—and understanding—chemical formulas pays off, not just in labs but everywhere chemistry touches our lives.

Is Copper Acetate Monohydrate hazardous to health?

Understanding What’s on the Table

Copper acetate monohydrate, a blue-green crystalline substance, catches the eye in chemistry labs and sometimes in industry. Those who work near it often wonder what kind of risk it brings. It’s not as notorious as cyanide or asbestos, but nobody should ignore the safety data.

Why It Matters: Health Risks from the Inside Out

The copper in copper acetate isn’t new to health discussions. Copper plays a necessary role in the human body, supporting enzymatic functions and iron absorption. There’s a line between essential nutrient and toxic pollutant, though. Go above that line, and trouble follows. Inhaling or ingesting too much copper acetate can upset the digestive tract, causing nausea, vomiting, and pain. If the levels climb even higher, the liver and kidneys start to suffer. I’ve seen data from the Hazardous Substances Data Bank showing that prolonged copper exposure can lead to metal fume fever, chills, and headaches, not just discomfort but genuine medical incidents that push people to seek care.

Lab workers sometimes tell stories about skin or eye irritation after accidental contact. The compound isn’t kind on the outside, either. Rashes, burning, and redness pop up fast, a reminder that even “simple” chemicals deserve respect. Dust in the air can also trigger respiratory issues for those with sensitivity or pre-existing conditions like asthma. Careless handling leads to contaminated workspace surfaces and accidental ingestion, something I’ve seen too many times during my years of mentoring new lab techs.

Digging Deeper: Long-Term Dangers

Copper toxicity rarely strikes overnight. It’s the result of routine exposure, often unnoticed. Beyond typical symptoms, studies link chronic overexposure to organ damage, immune problems, and possible disruption of mental functions. The National Institute for Occupational Safety and Health ranks copper salts like acetate among chemicals requiring rigid exposure limits for employees. This isn’t hypothetical; it’s spelled out in binding guidelines everywhere from Europe to North America.

Mitigating the Risk: Practical Steps

Overconfidence in a controlled environment breeds mistakes. Protective gloves, goggles, and respirators cut down the odds of contact or inhalation. I make it a habit to keep copper acetate in tightly sealed containers, away from food or drink areas, to limit accidental cross-contamination. Proper ventilation in workspaces pulls dust and vapors away from breathing zones, crucial for people handling powders or mixing solutions.

I’ve always pushed for updated Material Safety Data Sheets (MSDS), close at hand and easily understood by every worker, not just supervisors. When accidents or spills happen, prompt cleanup with appropriate neutralizers and disposal methods curbs risk to both humans and the environment. Training staff regularly on what symptoms to watch for and on emergency protocols keeps everyone sharper and safer. Good habits, thorough instruction, and respect for even “ordinary” compounds form the bedrock of a responsible approach.

Safer Paths Forward

Substitutes for copper acetate monohydrate do exist in some cases, especially in research settings, reducing direct risk. Where use is unavoidable, companies and educators should foster an open culture about hazards and report near-misses, not sweep them under the rug. The more transparent the conversation about chemical safety, the better equipped everybody will be to avoid problems before they grow.

How should Copper Acetate Monohydrate be stored?

Why Storage Choices Shape Lab Safety

Practical chemistry never runs out of reminders about respect. One lesson hits home fast: pay attention to chemical storage. Copper acetate monohydrate—a compound that shows up everywhere from high school labs to industrial use—deserves careful treatment. I’ve seen lab benches crowded with odd bottles and faded labels, and old blue-green crystals always catch the eye. In my years working around chemicals, splashy warnings don't stick as well as good habits. This is especially true when it comes to chemicals like copper acetate monohydrate.

Key Points for Safe Storage

Oxygen, moisture, sunlight, temperature swings—these all spell trouble for sensitive chemicals. Copper acetate monohydrate pulls water from the air, crumbles under direct sunlight, and doesn’t play nice with strong acids or bases. I learned early on to check storage containers regularly, and to never shove bottles close to the light or heat sources. Keeping the crystals sealed in a tightly closed container, tucked away from direct light, gives the best shot at keeping the stuff stable.

Temperature control stands out as an underrated detail. Most storerooms hover between 15 and 25°C, which is a comfortable middle ground for many inorganic salts. I once watched a bottle sweat all over a poorly ventilated shelf—humidity seeps through cardboard and old plastic. High-quality containers, made from glass or thick, chemical-resistant plastics, keep unwanted moisture out. Don’t trust lids that stick or containers with cracked threads. Moisture turns those vibrant crystals clumpy, eventually spoiling them for any meaningful lab work.

Why Ventilation and Separation Matter

Sometimes, people underestimate the risks attached to copper compounds. Inhaled dust, even a little, feels rough on the throat. I always double-check that storage cabinets have ventilation and signs signaling hazard. Proper separation can’t be ignored: acids and bases belong nowhere near copper acetate monohydrate. Contact between the two can fuel violent reactions or produce toxic gases. The National Institute for Occupational Safety and Health (NIOSH) highlights the hazards of copper exposure, and I’ve seen firsthand how cross-contact risks climb in crowded cabinets. Lab managers should run routine checks, reinforce safety training, and never let incompatible materials share a shelf.

Solutions That Last

Talk to anyone running a school or research facility, and you'll hear about the cost of replacing spoiled or contaminated chemicals. Saving money means more than bargain hunting on bulk orders. It means tightening up storage policy and scheduling periodic audits. Keeping an updated inventory with clear, readable labeling heads off accidental misuse. I remember more than one emergency, rooted in a moment’s confusion over a faded sticker or mystery powder.

For those working at home or in small labs, the same rules still apply. Use original containers where possible. Don’t improvise with food jars or unlabeled bags, especially with powders that look similar. Dispose of waste following local environmental guidelines. Copper salts, even in small amounts, pollute water and soil—dumping them down the drain remains a shortcut no real chemist would recommend.

Chemistry Built on Trust and Routine

Trust in a lab rests on little things. Clean containers, safe shelves, sharp eyes—these save lives and budgets, and respect the science itself. Copper acetate monohydrate isn’t the most dangerous chemical, but treating it with care becomes second nature with experience. Maintaining good storage routines shows respect for everyone who handles such materials, from researchers to janitors, and even to the students just starting out. That’s the kind of example I want to set, every single day.

What is the purity of your Copper Acetate Monohydrate product?

The Role of Purity in Everyday Work

In any lab, purity speaks louder than packaging. It’s always the first number chemists eye before running an experiment or setting up a reaction. I’ve seen more failed syntheses and troubleshooting meetings sparked by a small impurity than by almost any other factor. Usually, a copper acetate monohydrate product with a 98% or better assay fits most research and industrial needs. That sounds like plenty, but for applications like catalysis, high-purity plating, or advanced material development, even tiny contaminants start to matter. It’s frustrating to waste hours figuring out the source of a problem, only to trace it back to a trace metal or leftover solvent.

Purity Levels and Real-World Applications

Most listings you’ll find for copper acetate monohydrate hover around 98%-99% purity. The major difference between a bottle for the undergraduate teaching lab and a product for high-end electronics boils down to those last 1-2%. That percentage includes everything not copper acetate – water variations, mineral dust, trace heavy metals, and sometimes organic residues from old processes. For scientists trying to push the boundaries of thin film deposition, sensing, or catalysis, those trace impurities wind up in measurement data or, worse, corrode finished devices. Seeing poor yields can feel personal after investing weeks to prepare a batch, only to realize the culprit was hidden in the starting material.

Quality Testing and Trust

There’s always a gap between what’s printed on a label and what actually ends up in your beaker. Certificates of analysis should back up any claim about purity, showing either titration, ICP-MS, or X-ray fluorescence test results. Suppliers who update certificates for every batch give confidence. I remember once ordering the same product from two vendors – only one included a current test sheet, and the difference in end results for my experiment told the whole story. Publishing real analysis results helps both researchers and engineers avoid headaches downstream.

Purity Concerns Echo Beyond the Lab

Many forget that the knock-on effect of purity goes far beyond isolated failures. Any project building up from basic chemicals risks supply chain ripple effects if trace contaminants keep slipping through. I’ve talked to manufacturing engineers who’ve had to delay shipments because a single impurity triggered a flaw during quality checks. That material might get used for agriculture, food preservatives, or even as a starting point for medical imaging agents. So, purity controls protect not just the scientist or factory technician, but eventually, customers and even patients.

Building Confidence through Transparency

Most chemists want openness from suppliers. Listing the actual quantified impurities by type—lead, iron, sodium, for example—helps buyers assess fitness for purpose. Vendors who invest in regular third-party checks, not just internal assays, show they care about safety and reliability. I gravitate towards companies open to sharing specifics rather than hiding behind vague claims. Open lines help root out issues sooner, and build trust that pays off with repeat business and word-of-mouth recommendations.

Minimizing Risks through Smart Choices

Smart buyers ask for recent analysis, especially if results are crucial to downstream products. Upgrading to a certified, high-purity batch for critical steps pays dividends in fewer failed experiments and increased product reliability. Setting up internal checks such as spot-checking new batches with in-house methods can catch rare outliers. Purity data matters more than branding, and consistent test results win loyalty every time.

Copper Acetate Monohydrate
Copper Acetate Monohydrate
Copper Acetate Monohydrate
Names
Preferred IUPAC name copper(II) acetate monohydrate
Other names Cupric acetate monohydrate
Copper(II) acetate monohydrate
Acetic acid, copper(2+) salt, monohydrate
Pronunciation /ˈkɒpər əˈsiːteɪt ˌmɒnəˈhaɪdreɪt/
Identifiers
CAS Number 6046-93-1
Beilstein Reference 3587158
ChEBI CHEBI:131379
ChEMBL CHEMBL1233066
ChemSpider 16317
DrugBank DB14536
ECHA InfoCard 100.012.404
EC Number 204-170-3
Gmelin Reference 71580
KEGG C00382
MeSH D003975
PubChem CID 14767
RTECS number GL7875000
UNII 72LU97RA1S
UN number UN3077
Properties
Chemical formula Cu(C2H3O2)2·H2O
Molar mass 199.65 g/mol
Appearance Blue-green crystalline solid
Odor Odorless
Density 1.88 g/cm³
Solubility in water 7.2 g/100 mL (20 °C)
log P -2.6
Acidity (pKa) 4.8
Basicity (pKb) 9.4
Magnetic susceptibility (χ) −0.95×10⁻⁶ cm³/mol
Dipole moment 5.85 D
Thermochemistry
Std molar entropy (S⦵298) 155.5 J·mol⁻¹·K⁻¹
Std enthalpy of formation (ΔfH⦵298) -971.2 kJ/mol
Std enthalpy of combustion (ΔcH⦵298) -1507 kJ/mol
Pharmacology
ATC code A16AX14
Hazards
Main hazards Harmful if swallowed. Causes serious eye irritation. Causes skin irritation. May cause respiratory irritation.
GHS labelling GHS02, GHS07
Pictograms GHS07,GHS09
Signal word Danger
Hazard statements H302: Harmful if swallowed. H410: Very toxic to aquatic life with long lasting effects.
Precautionary statements P264, P270, P273, P280, P301+P312, P302+P352, P304+P340, P305+P351+P338, P312, P332+P313, P337+P313, P362+P364, P501
Explosive limits Not explosive
Lethal dose or concentration LD50 oral rat 710 mg/kg
LD50 (median dose) LD50 (oral, rat): 710 mg/kg
NIOSH Not established
PEL (Permissible) PEL: 1 mg/m³
REL (Recommended) 10 mg/m³
IDLH (Immediate danger) 100 mg/m3
Related compounds
Related compounds Copper(II) acetate
Copper(II) oxide
Copper(II) sulfate
Copper(II) carbonate
Copper(I) acetate