Nanjing Liwei Chemical Co., Ltd

Знание

Nickel Acetate: A Deep Dive into Its Journey, Uses, and Impacts

Historical Development

Nickel acetate didn't just spring out of nowhere; it’s rooted in the progress of industrial chemistry. Early nickel compounds trace back to the 18th century, when nickel itself got recognized as a distinct element. The use of salts like acetate surfaced as the needs of industries grew more complex during the Industrial Revolution. Electroplating processes boomed in the 20th century, and that's where nickel acetate found a steady footing—helping establish corrosion-resistant surfaces, a crucial step for industries like automotive and consumer electronics. These roots reflect the close link between chemical innovation and everything from durable coins to fancy gadgets, giving real weight to the study and manufacturing of these metal-organic salts.

Product Overview

Nickel acetate shows up as a green crystalline substance, standing out in the catalog of organonickel compounds. Laboratories and factories both count on it for tasks that blend practicality with precision. It serves as a go-to solution for nickel plating, dye mordant, and as a catalyst. Some may overlook how often it pops up in modern manufacturing: printed circuit boards, metal finishing, or even in research on hydrogen storage. The salt, with its unique structure, forms a bridge between pure academic curiosity and the nuts-and-bolts needs of global markets. Identifying its green color and crystal habit isn’t just about chemistry; it’s about recognizing the silent workhorses in daily products.

Physical & Chemical Properties

Nickel acetate typically appears as emerald-green crystals with noticeable solubility in water and a moderate melting point. Its formula—Ni(CH3COO)2·4H2O—points to its four waters of hydration, which influence both its appearance and reactions. Water affinity determines not just shelf-life, but also how it performs in technical setups. The acetate group interacts flexibly with organic and inorganic reagents, while the nickel ion stays ready for redox processes. It decomposes above 250°C, giving off acetic acid fumes and nickel oxide, and people should always watch out for these by-products in labs or pilot plants.

Technical Specifications & Labeling

Factories and chemical distributors offer nickel acetate with purity generally above 98%. Labels call attention to batch number, molecular weight, water content, and expiration date. Safety data sheets flag hazardous components, which align with global harmonization standards, bearing pictograms for acute toxicity and environmental hazard. Producers use lot numbers for careful tracing, making recalls and regulatory compliance more approachable instead of an afterthought. Attention to labeling isn't only legal; it earns trust from workers and customers who depend on transparency for safe handling.

Preparation Method

People prepare nickel acetate by reacting nickel carbonate or nickel hydroxide with acetic acid under controlled temperatures. This reaction doesn't need exotic conditions—normal glassware and temperature regulation often do the trick. After stirring, filtration clears up insoluble impurities, and careful evaporation crystallizes the product. On an industrial scale, stainless steel reactors handle larger volumes, and operators focus on maintaining steady pH and avoiding dust emissions. Purified crystals get dried and bagged in moisture-proof containers. The entire process offers a hands-on lesson in balancing efficiency, safety, and material costs, showing that even "simple" reactions deserve close attention.

Chemical Reactions & Modifications

Nickel acetate behaves flexibly in synthesis. In nickel plating baths, it supplies nickel ions, which deposit as thin layers when an electric current passes through the solution. As a precursor, it feeds into the preparation of nickel catalysts by gentle thermal decomposition, producing fine nickel oxide powders. Chemists tweak the acetate's structure by adding chelators, swapping out water molecules with other ligands, and building metal-organic frameworks for battery and sensor research. It also reacts with phosphines, amines, or silica surfaces, showing how versatile it has become in both old and brand-new applications.

Synonyms & Product Names

You’ll hear nickel acetate called by several aliases: Nickel(II) acetate, UNII-8OY65VBE6I, or simply NiAc. In regulatory parlance, it can bear numbers like CAS 373-02-4 for its tetrahydrate form. Trade catalogs may use names like “Nickel acetate tetrahydrate, reagent grade” or “Nickel diacetate.” Even these small variations can send buyers or researchers to different grades or purity profiles. Recognizing synonyms isn’t just a dictionary task—it makes sure orders, safety reports, and compliance paperwork stay accurate, cutting down on costly mix-ups.

Safety & Operational Standards

Nickel acetate, while essential, brings health concerns. Direct exposure causes skin and respiratory irritation, and in severe cases, sensitization. The compound finds its way onto lists for suspected carcinogens. Most countries place restrictions on workplace airborne concentrations, requiring fume hoods, gloves, respirators, and tight storage protocols. Training on spills, waste disposal, and emergency eye-wash stations isn’t burdensome detail—it’s a shield for workers’ health. Following REACH and OSHA standards means operations run with fewer accidents, clear legal standing, and a workforce that knows its safety comes first.

Application Area

Metal finishing dominates nickel acetate’s user base, especially in sealing anodized aluminum. The coating, formed through dipping or spraying, blocks corrosion and boosts lifespan—from smartphones to architectural panels. The textile sector has relied on it for setting colors with certain synthetic dyes. Research labs treat it as a precursor for nanoparticle synthesis, catalysis, and battery development. Medical device firms explore it to modify surface biocompatibility, while the ceramics industry uses it for coloring glazes. The sheer spread underscores its utility across setups both high-tech and traditional.

Research & Development

Nickel acetate sits at the intersection of industrial demand and scientific curiosity. Material scientists keep testing new blends and morphologies to enhance battery performance or fine-tune nanomaterials. There’s steady progress in lowering residual nickel content in final products for safer consumer goods. Academic research pursues green chemistry methods, swapping harsh acids for milder paths and recovering nickel from waste using bio-based acids—aiming to close recycling loops wherever possible. Tech startups investigate how to harness nickel acetate for greener hydrogen production or porous catalyst scaffolds, blending old-school chemistry with cutting-edge technology.

Toxicity Research

Research into the health impacts of nickel compounds widened over recent decades. Chronic exposure links to dermatitis and heightened cancer risk, with finer studies examining DNA-binding tendencies and cellular toxicity. Animal studies reveal immune and respiratory effects, while occupational health surveys track absorption levels by urine and blood sampling among metal workers. Regulatory tracking by the EU, US EPA, and other agencies forces continuous toxicity reassessment. The push for safer substitutes underlines a trend: the chemistry community no longer shrugs off the side effects of heavy metals, bringing personal protection equipment and risk monitoring to the forefront.

Future Prospects

Nickel acetate’s story looks far from finished. Researchers chase cleaner synthesis routes with less waste and energy use, joining the race for more sustainable raw materials. The electric vehicle boom stokes demand for improved nickel-based batteries, nudging chemists toward more active and recyclable nickel salts. Big data and AI may guide the discovery of next-generation nickel compounds that leapfrog current limitations. Policy trends around green chemistry and stricter occupational standards will likely reshape production practices, making safety and sustainability as important as cost and performance. These shifts send a message: chemistry’s quiet players, like nickel acetate, often ride at the front of industrial change.



What is Nickel Acetate used for?

The Real-World Role in Metal Finishing

Nickel acetate steps into the spotlight mostly in the world of electroless nickel plating and post-plating treatments. Plenty of people walk through buildings or drive cars every day, unaware of the protective barriers that keep metal parts going strong. Take window frames, plumbing fixtures, or the undercarriages of cars—most owe their corrosion resistance to surface treatments, with nickel acetate a key player in that story. It reacts with nickel-plated surfaces, sealing microscopic pores and helping to keep rust at bay. Without that step, nickel coatings on faucets or industrial tools wear down sooner, inviting corrosion and replacement costs.

Inkjet Printing and Technology

Printers in homes and offices worldwide rely on complex chemistry for reliable color and ink flow. Nickel acetate contributes as a stabilizer and bonding agent in certain inkjet inks. It helps fix dyes or pigments to paper more precisely. Reliable printouts matter for everything from report cards to contracts. Getting vivid, sharp images keeps businesses professional and families proud of their snapshots. If print quality slips, it often means wasted materials and frustration—something better chemistry helps prevent.

Textile Dye Fixation

Clothing makers deal with a challenge: getting dyes to stick to fabrics through countless washes and sunny days. Nickel acetate acts as a mordant for some dyeing techniques. It anchors dye molecules to the fibers, locking in color. The science here affects anyone who’s pulled a favorite T-shirt out of the wash only to find it pale or patchy. The disappointment is real. A more permanent bond keeps shoppers satisfied and cuts down on textile waste—important as people push for more sustainable fashion.

Laboratory Work and Research

For chemists and students, nickel acetate serves as a reliable source of nickel ions in lab reactions. Nickel shows up in catalysts, batteries, and sensors, making it a regular guest on research benches. Many battery prototypes for renewable energy storage rely on electrodes made with nickel compounds. Each small discovery in a university lab plays its part in building better batteries and cleaner technologies for tomorrow.

Health and Environmental Notes

Safety always matters. Nickel compounds can trigger allergic reactions and have potential toxicity when mishandled. People who work with nickel acetate in plating shops or dye factories often face strict guidelines—protective gloves, proper ventilation, and regular training. Diluted wash water and nickel-laden rags require careful disposal. Factory managers must track releases and stick to tight disposal standards so local water and soil stay clear of nickel contamination. Even hobbyists tinkering with metal finishes at home benefit from knowing the risks and using caution.

Looking Toward Greener Solutions

The world asks more of manufacturers these days. Cleaner products and better recycling go hand-in-hand with the use of chemicals like nickel acetate. Alternatives arrive from ongoing research—some processes look for entirely nickel-free methods, or swap in less hazardous sealants and mordants. People who buy coated metals, colorful textiles, or household printers play a role by supporting businesses with transparent supply chains and strong recycling programs. Adopting safer work practices in factories, investing in green chemistry, and demanding accountability from manufacturers all help keep the benefits of nickel acetate without the unwanted side effects.

Is Nickel Acetate hazardous or toxic?

Nickel Acetate in Everyday Life

Walk into a shop where they plate metals, or visit a place where art meets chemistry, and you might catch a glimpse of bright green crystals labeled nickel acetate. Some folks use it for dyeing, others for nickel plating, and some chemists play with it in the lab every day. It doesn’t look dangerous. That green hue makes it stand out, but it’s easy to forget—looks betray the risks.

Health Risks That Lurk Beneath

Breathing in nickel compounds—or getting them on your skin over and over—can cause problems. I once spent a summer in a metal finishing plant, and nobody there took the warnings lightly. If you don’t use gloves, or if you let dust collect on your clothes, you might pay with rashes or something worse. Nickel becomes a big issue for folks with allergies. A patch of skin can swell up, itch for days, and break into blisters that stick around longer than anyone wants. The CDC and NIOSH have talked about nickel’s role in causing asthma and chronic respiratory issues when dust or fumes get into the air. I remember, our supervisor would never let us work without masks or proper ventilation running.

Long-Term Exposure and Leading Risks

Nickel acetate isn’t just about occasional irritation. Studies by the International Agency for Research on Cancer (IARC) and OSHA link nickel and its compounds to a higher chance of getting cancer, especially lung and nasal cancers. Plating jobs and labs that skip safety steps often see more cases of sickness over the years. Just because nickel acetate doesn’t carry a skull-and-crossbones icon doesn’t mean it gets a free pass.

What Facts Teach Us

Peer-reviewed studies keep nudging regulations forward. Researchers describe nickel acetate as hazardous on Sigma-Aldrich and PubChem due to its potential for toxicity. High exposure in animals brings on DNA damage. Human exposure can lead to kidney and lung effects when people let their guard down. Young workers just starting out can fall into the trap of skipping protective gear. Older hands on the job know that one day of carelessness can lead to weeks of trouble.

Daily Practices That Matter

I learned to read chemical safety data sheets and treat every powder as risky. Washing up after handling, never eating around the work area, and keeping work clothes separate from home gear all cut down personal exposure. Mask fit checks keep fine dust out, and having a strong set of rules makes the workplace safer for everyone. Companies that offer good protective gear, and regular health checks for those around nickel salts, stand out from the rest. They send workers home healthy—day after day, year after year.

Steps Toward Safer Work

Better engineering controls—like enclosed processes and strong ventilation—take out most of the hazard. Regular air quality checks spot trouble before anyone starts coughing. Substituting chemicals for less harmful ones is a long-term goal. Training matters, too; learning from stories, not just rules, sticks in people’s minds. Laws and best practices have moved a long way since people first started nickel plating. But as demand grows, vigilance can’t drop.

Looking Out for Each Other

No one does this alone. Covering up, washing off, and working with the right equipment isn’t about paranoia. It’s common sense, rooted in experience and science. Nickel acetate doesn’t announce its presence like a rotten egg smell or harsh fumes, so trust in routine can become a trap. Those green crystals carry more than color—they carry a call for respect. That’s worth remembering, whether you’re a scientist, a worker, or just curious about what those chemicals can do.

What is the chemical formula of Nickel Acetate?

The Basics Behind Nickel Acetate

Nickel acetate turns up often in labs and factories. Most folks who use it know it by its formula, Ni(CH3COO)2·4H2O. Each molecule brings together nickel, acetate groups, and water. If you see a green powder in a glass jar marked with that formula, you’re looking at nickel(II) acetate tetrahydrate. It’s got two acetate ions for every single nickel ion, plus four water molecules hanging on. The powder dissolves easily in water, and this makes it handy in plating and textile dyeing.

Real Life Uses Go Far Beyond Chemistry Books

Folks who work in surface finishing run into this compound more than once. In electroplating shops, workers use nickel acetate to seal anodized aluminum parts. Anodized coatings pick up extra durability when treated with this salt. In my time speaking with technicians, they all highlighted one thing: using the right formula and pure materials stops equipment failure. No one wants to see parts corrode from poor sealing. Nickel acetate does its job well when prepared right, and many factories rely on that reliability to keep costs down and customers happy. It also pops up in the world of ceramics and dyes, lending that characteristic pale green to glass and pottery glazes.

Staying Safe With Nickel Acetate

Anyone working in science or manufacturing has to pay attention to safety. Nickel acetate can irritate skin, lungs, and eyes. Inhaling the dust poses long-term health risks. Regulations call for good ventilation and protective gear. In one shop I visited, managers laid out strict rules about storage—no containers left open, and everything labeled properly. They understand the risks. Regular training, along with posted hazard sheets, helps protect workers handling the compound every day.

Environmental Impact and Responsible Handling

Factories and research centers generate waste, and waste containing heavy metals causes trouble for the environment. Nickel acetate shouldn’t go down the drain. Environmental groups have tracked how heavy metals move in water supplies, and nickel isn’t something you want in your drinking water. Recycling or properly neutralizing waste in treatment plants matters. The Environmental Protection Agency calls for strict controls on nickel release, and companies get hefty fines if they slack off. Responsible firms set up capture systems—treatment tanks, ion exchangers, methods that cut nickel discharge close to zero. This all protects local rivers and lakes from pollution and keeps communities safer.

Finding Better Approaches

Switching to cleaner alternatives regularly crops up in industrial talks. Some engineers have begun experimenting with water-based sealing agents or ceramic finishes that cut out heavy metals. These new approaches work well for certain applications but don’t always match the durability of good old nickel acetate. R&D teams keep testing solutions, motivated by the need to lower toxicity and slash costs. Collaboration between industry, regulators, and researchers has brought real progress already. Lessons learned in one sector slowly trickle into others, nudging everyone toward cleaner, safer practices.

Wrapping Up the Main Points

Nickel acetate’s formula and properties seem simple: one nickel ion, two acetate ions, and four water molecules. Yet behind that simplicity hides a compound relied upon in factories and labs around the world. Respect for its power, an awareness of safety, and a commitment to handling waste with care—these remain essential in every workplace using nickel acetate. As long as teams keep sharing knowledge and exploring safer process technologies, society stands better equipped to protect both workers and the world outside factory gates.

How should Nickel Acetate be stored?

Understanding Nickel Acetate’s Hazards

Anyone who works with chemicals learns fast that some materials ask for special attention. Nickel acetate falls firmly into that group. With a light green color and a reputation for use in electroplating, it sounds simple enough, but handling turns risky when folks cut corners. Inhaling dust or ingesting nickel compounds can lead to toxic effects. That alone sets the standard: if you stock this compound in a lab or shop, you owe it to everyone around you to get storage right.

Control Humidity and Limit Exposure

Nickel acetate absorbs moisture, which means humidity creates headaches both for storage and long-term stability. Moisture can clump the powder, spoil batches, or encourage unwanted reactions. I have seen containers stick shut from damp, and sometimes labels even peel off, which invites mistakes. Dry cabinets or sealed containers block this from happening. Desiccants work wonders in glass jars or plastic containers made for chemicals—just toss in a silica packet, and the contents stay dry.

Store Away From Heat and Sunlight

Direct sunlight and high heat can ruin more than just nickel acetate's look. Heat may encourage decomposition, which means more fumes and potential surprises. A cool, shaded cabinet inside a ventilated chemical storeroom helps deliver peace of mind. Never place storage shelves near radiators or sunny windows. If you use an outdoor building, check the thermometer if the weather shifts. Keeping temperature stable reduces risk and keeps the chemical reliable for longer.

Protect Against Mix-Ups

A simple label stands guard against confusion. I’ve watched someone reach for the wrong bottle more than once, and with nickel compounds, mistakes can harm workers and the environment. Big, bold labels declaring both the substance and hazard type keep everybody on track. For teams with multiple languages, add extra stickers and safety symbols. Consider color-coding shelf spaces too, since quick glances save costly mistakes during busy shifts.

Use the Right Containers

It’s tempting to reuse empty bottles or old jars, but not every container resists corrosion. Nickel acetate reacts with metals, so stick with containers made from glass or high-grade plastic. Always use lids that seal completely. In labs I’ve worked in, people sometimes trust plastic bags—they tear, spill, or even leach chemicals. Rigid jars or factory-sealed tubs pay for themselves by preventing loss and protecting air quality.

Separate Incompatibles

Mixing chemicals causes most workplace accidents, and nickel acetate doesn’t make exceptions. Keep it separated from strong acids, strong bases, and any oxidizing agents. I once saw someone shelve acids too close to nickel salts; a tiny spill led to noxious fumes and an emergency call. Separate shelves or storage bins for incompatible items help prevent this, and training workers to spot hazard categories can boost safety across the whole crew.

Backup Safety With Regular Checks

Rarely does a label stay readable forever. Containers sometimes show cracks or spread powder around their rims. Regular checks cut the odds of accidents and remind workers to replace packaging before leaks begin. I recommend monthly walk-throughs, clipboards in hand, noting container dates, condition, and any changes in chemical appearance. This habit costs nothing but pays back with peace of mind and fewer cleanup headaches.

Community and Compliance

No storage plan works without people. Talk through storage rules, demonstrate safe handling, and invite questions at every meeting. Follow local rules for hazard storage—agencies such as OSHA and environmental offices often post clear guidelines. With so many lives wrapped around workplace chemicals, treating nickel acetate with respect means every shift stays accident-free and every worker heads home safe.

What are the physical properties of Nickel Acetate?

The Look and Feel of Nickel Acetate

Nickel acetate comes as bright green crystals or sometimes a green powder. The color strikes you right away—hard to confuse with anything else on the shelf. In the hand, it clumps together, and those crystals feel less gritty than common table salt, with much more of a slick, fine touch. Moisture from the air sticks to it, and over a humid summer, a container of open nickel acetate may clump or turn a bit damp.

Solubility and Smell

This compound dissolves easily in water, making a clear, greenish solution. If you make up a bath for an electroplating process, it dissolves quickly, without stubborn grains at the bottom of the beaker. You won’t catch much of a smell from nickel acetate, unlike ammonia-based nickel solutions, which can burn the nose. Nickel acetate also mixes well with alcohol, but not so much with other organic solvents—pouring it into something like acetone or ether leaves you with a mess at the bottom of your flask.

Melting Point and Stability

This compound starts falling apart at relatively low heat, breaking down to form nickel oxide and acetic acid somewhere around 250°C. Keep that in mind before any process that might push temperatures toward that range, as heating it up destroys the green color and releases some sharp fumes. In the lab, nobody stores nickel acetate near the furnace for this reason.

Density and Weight

Nickel acetate crystals feel heavier than pure salts like sodium chloride. The density sits around 1.7 grams per cubic centimeter, so a full bottle gives a solid heft in your hand. This makes dosing for chemical reactions easy enough: you know right away whether you scooped enough or not. That same density helps with storage and weighing, as a controlled scoop gives you reliable results each time.

Hygroscopic Nature

Nickel acetate likes water. Leave it in the open air, and it slowly draws moisture, making lumps and even pools of green liquid if the humidity stays up. This property means someone using it in the factory or lab should always keep the lid shut between uses. The crystals stick together if handled with wet gloves or left in an open bag. Over time, any exposed powder might become sticky or pasty, which creates some hassle for precise measurements or mixing.

Hardness and Handling

You won’t cut yourself on sharp edges, as crystals of nickel acetate break apart almost as easily as dried mud. Dropping a vial doesn’t send shards scattering; the crystals just become powder. Gloves are a must, not only because dust might irritate or cause allergies, but because nickel salts can sensitize some people over time.

Effects on Everyday Use

For anyone running a plating shop, these physical qualities save time and trouble. Solutions don’t need hours to mix. The color makes it easy to spot spillage, and the density allows for quick mass-to-volume conversions. Its lower melting point and tendency to absorb water mean tighter control of environment and storage. Over the years, many workers learn to watch the weather on humid days, as containers that aren’t sealed may gum up at just the wrong time. Simple habits—quick wipe-downs, using dry scoops, sealing after each use—make work smoother and safer.

Nickel Acetate
Nickel Acetate
Nickel Acetate
Names
Preferred IUPAC name Nickel(II) diacetate
Other names Acetic acid nickel(2+) salt
Nickel(II) acetate
Nickel diacetate
Nickel(II) acetate tetrahydrate
Pronunciation /ˈnɪk.əl ˈæs.ɪ.teɪt/
Identifiers
CAS Number 373-02-4
Beilstein Reference 3535643
ChEBI CHEBI:84956
ChEMBL CHEMBL1233507
ChemSpider 54670
DrugBank DB11090
ECHA InfoCard 100.028.293
EC Number 209-170-2
Gmelin Reference 610883
KEGG C02381
MeSH D009538
PubChem CID 8892
RTECS number QR6125000
UNII Q40Y5O397F
UN number UN3077
CompTox Dashboard (EPA) DTXSID9020436
Properties
Chemical formula Ni(C2H3O2)2
Molar mass 248.845 g/mol
Appearance Green crystals or powder
Odor Odorless
Density 1.744 g/cm³
Solubility in water Soluble
log P -1.7
Vapor pressure Negligible
Acidity (pKa) 7.52
Basicity (pKb) pKb: 6.28
Magnetic susceptibility (χ) +1.18×10⁻⁴ (SI)
Refractive index (nD) 1.546
Dipole moment 9.23 D
Thermochemistry
Std molar entropy (S⦵298) 155.8 J·mol⁻¹·K⁻¹
Std enthalpy of formation (ΔfH⦵298) -1012.7 kJ/mol
Std enthalpy of combustion (ΔcH⦵298) –1517.7 kJ·mol⁻¹
Pharmacology
ATC code V07AY17
Hazards
Main hazards May cause allergy or asthma symptoms or breathing difficulties if inhaled; May cause an allergic skin reaction; Suspected of causing genetic defects; May cause cancer; Harmful if swallowed; Toxic to aquatic life with long lasting effects.
GHS labelling GHS07, GHS08
Pictograms GHS07,GHS09
Signal word Warning
Hazard statements H317, H334, H350i, H372, H412
Precautionary statements P264, P280, P302+P352, P305+P351+P338, P321, P332+P313, P337+P313, P362+P364, P501
NFPA 704 (fire diamond) 2-1-0
Lethal dose or concentration LD50 oral rat 350 mg/kg
LD50 (median dose) LD50 (median dose): Oral rat LD50 = 350 mg/kg
NIOSH WW3675000
PEL (Permissible) 1 mg/m3
REL (Recommended) 0.1 mg Ni/m³
IDLH (Immediate danger) 250 mg/m3
Related compounds
Related compounds Nickel(II) chloride
Nickel(II) sulfate
Nickel(II) nitrate
Nickel(II) carbonate