Nanjing Liwei Chemical Co., Ltd

Знание

Stannous Oxide: An In-Depth Look

Historical Development

Stannous oxide carries a history stretching back to the days when early chemists first separated metals from minerals. Once tradespeople saw metallic tin could react with oxygen, they got curious. Ancient artisans, especially those making bronze, must have stumbled upon different tin oxides as side-products. By the 19th century, stannous oxide found a spot in lab work and in production processes. Researchers spent time figuring out its differences from stannic oxide, since both pop up during smelting. Improvements in separation methods and purity control started as industries demanded better quality for electronics and specialized glass. Each decade has offered new ways to tailor and purify stannous oxide, making a familiar compound almost new with each generation.

Product Overview

Stannous oxide shows up as a blue-black or brownish powder. Most material on the market gets sold to manufacturers looking for reliable reducing agents, catalysts, or glaze ingredients. Firms that handle this product keep a close eye on batch quality, knowing that even trace oxidation to stannic variants ruins some applications. Physical appearance alone doesn't always tell you enough; experienced users check for texture and how it interacts with air and moisture. Pure batches absorb oxygen easily, so packaging and storage become part of the product’s identity.

Physical & Chemical Properties

This compound, SnO, has a specific molecular weight of about 134.71 g/mol. Its structure holds up as a crystal lattice, and you’ll find it decomposing above 300°C, releasing metallic tin and oxygen. Stannous oxide resists dissolving in water but reacts fast in strong acids or alkali, which helps explain its role in several industrial processes. Its stability depends a lot on how it’s made and stored. In poorly sealed containers, it draws oxygen from the air, slowly oxidizing to stannic oxide, so exposure means gradual loss in chemical strength for certain uses. Color can shift slightly depending on particle size and preparation method, providing a quick, though imperfect, check for trained eyes.

Technical Specifications & Labeling

Modern supply chains demand precise specification sheets. Commercial stannous oxide gets labeled by purity, particle size, and any trace contaminants. The best grades contain over 99% SnO, with clear limits for iron, lead, and antimony. Labelling under globally recognized systems like GHS signals toxicity and hazard, backed by Material Safety Data Sheets. Shipment labels flag its tendency to oxidize, and some suppliers cover containers with inert gas. Payment often links to compliance with standards set by ASTM or ISO. These documents matter in quality control, making sure raw material feeds work as intended into chemical reactions or product formulations.

Preparation Method

Hotly debated, the best preparation depends on final use and desired purity. Lab workers often reduce stannic oxide with hydrogen, wielding careful temperature control for best results. Other setups opt for the direct oxidation of tin metal in air, but only in low-oxygen atmospheres, to block further oxidation to stannic oxide. Some manufacturers introduce carbon monoxide as a reducing agent, especially when purity isn’t as critical. Small-scale syntheses can even happen in test tube—powdered tin heated in an evacuated tube with limited oxygen supply. Waste products, especially tin(IV) oxide, call for disposal or recycling, underscoring the importance of clean process design.

Chemical Reactions & Modifications

Stannous oxide acts as a reliable reducing agent, and it can convert certain metal oxides to elemental form. In acids, it often produces double salts, sometimes useful in analytical chemistry. It has a knack for disproportionation, shifting between tin(II) and tin(IV) compounds. This reaction can frustrate or help chemists, depending on context. For those who work with ceramic glazes or colored glass, the ability of stannous oxide to donate or accept electrons provides a useful palette of hues and effects. Further tweaks by adding dopants result in modified oxides with unique electrical or catalytic properties, opening doors for specialized sensors and even solar cell components.

Synonyms & Product Names

Over the years, stannous oxide travelled under names like tin(II) oxide, tin monoxide, and ancient texts sometimes refer to it as protoxide of tin. Catalogs group it as SnO, matching IUPAC conventions. Each alias might carry a slightly different reputation among researchers—older literature sometimes mentions it under outdated mineralogical terms, but most commercial buyers stick with standard nomenclature for clarity.

Safety & Operational Standards

Companies handling stannous oxide train workers to watch for dust inhalation and skin contact. Practioners know it doesn’t pose the heavy risks tied to many metallic compounds, but breathing it or letting it get in eyes still brings irritation. Gloves, goggles, and dust masks line the benches in production spaces. As batch sizes and use volumes rise, facilities install ventilation and dust collection. Waste from old or spilled powder gets sealed by local environmental rules, and compliance audits focus on safe storage—airtight containers, away from strong oxidizers. Companies post hazard warnings throughout storage rooms out of respect for changing workforce and shifting regulatory climates.

Application Area

Stannous oxide claims real territory in ceramics and glass. As a coloring and opacifying agent, it influences how glazes mature and finish. In surface coatings, SnO controls sheen and durability, especially for goods that see heat or chemical stress. Some manufacturers use it in low-temperature solder pastes, where stable properties help form reliable joints. Certain gas sensors rely on modified stannous oxide as a detecting layer. In laboratory settings, chemists value its reducing power during delicate synthetic steps. The pharmaceuticals industry has dabbled with it in radiopharmaceuticals. Years of learning refine which grades and forms best tackle each application, pushing buyers and sellers to share best practices.

Research & Development

In today’s research labs, scientists keep probing for more ways to engineer stannous oxide for targeted technology. Thin film specialists work on tuning SnO properties for transparent electrodes. Materials scientists tinker with nano-sized stannous oxide to improve sensors and battery anodes. Ongoing research tracks how structural modifications at the molecular level flip conductivity or reactivity, supporting efforts to design better semiconductors and transparent conducting films. University teams frequently test combinations with other oxides to explore soft-matter electronics and next-gen optoelectronic components. Each experiment builds on hard-won lab experience and a growing base of peer-reviewed studies.

Toxicity Research

So far, toxicity studies show stannous oxide doesn’t threaten human health at everyday exposure levels. Chronic inhalation of dust could irritate airways, and animal studies support calls for caution in occupational settings. Researchers haven’t linked environmental or bioaccumulative danger to stannous oxide, but they keep checking for subtle effects as analytical methods improve. Regulatory bodies still set workplace exposure limits, based on both animal testing and case histories of manufacturing workers. Data from government and academic datasets guide label warnings and the design of protective protocols. Reliability in safety claims comes from repeated measurements and transparent disclosure of uncertainty, ensuring workers understand the real risks.

Future Prospects

Looking ahead, stannous oxide earns attention in advanced energy storage, solar technology, and waste recovery. Trends in green chemistry push researchers to replace nastier reducing agents with friendlier alternatives like SnO. As battery makers look for new anode materials, the tin-oxide family creates excitement for boosting power without sacrificing lifespan. Environmental scientists examine SnO for water treatment processes, focusing on trace contaminant removal. Ongoing pilot projects measure real-world performance, and the push for better digital sensors keeps labs interested in stannous oxide for its tailored conductivity and surface chemistry. Each new use story emerges from continued investment and trial-and-error at the lab bench, proving that even a well-known chemical has room for reinvention as technology advances.



What is Stannous Oxide used for?

Stannous Oxide: Not Just a Lab Curiosity

Stannous oxide doesn’t pop up in neighborhood conversations. Most people haven’t heard of it, and if they have, they probably remember it from a dusty spot in high school chemistry class. In practice, this compound ends up living a much more interesting life. I’ve seen how its role stretches across industries that touch everyday products, sometimes in ways many people would never guess.

A Sturdy Player in the World of Ceramics and Glass

Any cup, plate, or tile with a deep glaze might owe some of its luster to stannous oxide. Potters and industrial manufacturers turn to this compound for its strong reducing properties. The way it works in a ceramic glaze reminds me of seasoning a dish—getting the color just right takes practice and the right ingredients. Stannous oxide helps create rich, opaque whites and nutty browns. Years ago, I visited a family pottery studio, and they pointed out the remarkable difference a trace amount of the oxide could make in a large kiln batch. In glassmaking, it often acts as a decolorizer, removing that odd green tint impurities can leave behind. The clear glass in a window or a wine bottle sometimes owes its clean look to this chemical intervention.

Backbone of Modern Electronics

Many electronics rely on materials that can shift how electricity moves. Stannous oxide plays its part here. It’s used in making certain types of sensors and conductive coatings. I remember a friend in an electronics lab showing me how oxides like this one form thin films that help control circuits or create sensitive detectors. Without these specialized layers, devices would lose both accuracy and efficiency.

Careful Chemistry in Everyday Products

Dentists talk about stannous compounds often, especially in toothpaste. Stannous fluoride usually gets the headline, but stannous oxide sometimes supports these formulas behind the scenes. It helps deliver protective properties—reducing sensitivity or shielding teeth from decay. Having relied on recommendations from my dentist, I started to appreciate that sound chemistry makes for a healthier smile. This connection between industrial chemistry and personal health brings the conversation from the lab bench right to the bathroom sink.

Risks, Responsibility, and a Road Forward

Stannous oxide can be tricky. Its handling in factories and labs needs strong oversight because it can create dust, which isn’t good to breathe in large amounts. Safety guidelines exist for a reason: respiratory protection and proper training matter. Instead of ignoring the risks, we should look for methods to update manufacturing systems, introduce safer substitutes where they work just as well, and strengthen workplace education.

Finding reliable suppliers also matters, especially with increasing global demand in high-tech sectors. Companies that dig deep into ethical sourcing and safety certifications set a positive example. Better regulation and transparency can help cut down on counterfeit, adulterated, or poorly manufactured chemical supplies, which protect both workers and end users.

The Value of Chemistry in Small Quantities

Stannous oxide shows that even tiny amounts of the right material can transform products and make them safer or more appealing. Keeping both eyes on how it’s sourced, used, and controlled can open up new possibilities—while keeping people and the environment out of harm’s way.

What is the chemical formula of Stannous Oxide?

What Stannous Oxide Really Is

Stannous oxide goes by the formula SnO. That’s tin in its +2 oxidation state, paired up with oxygen. People run across this compound in fields from materials science to everyday chemistry, not just labs but in industries where reliability makes or breaks a process. If someone has spent time doing high school chemistry, they might remember the two forms of tin oxides. Stannic oxide (SnO2) gets most of the early attention, but stannous oxide plays a different game, thanks to that lower +2 state. Here, it’s not just about what goes on paper; the nature of the chemical changes how it behaves in real-world applications.

Why SnO Matters in Practice

The world relies on tin compounds for soldering, glass-making, and even in ceramics. Take solder: Reliable electronics need connections that stay consistent. Stannous compounds help control the characteristics of solder, affecting melting point and durability. I’ve known engineers who swear by a particular batch of tin oxide for ensuring circuit boards last, with fewer breakdowns under heat or stress. Making glass isn’t just pouring sand and hoping for a window. Manufacturers count on precise chemical reactions to create glass that doesn’t cloud up or weaken. SnO helps control color and other properties during production. You spot variations in batches, and a small shift in the chemical mix can kill a month's productivity or spike costs.

Facts Behind Stannous Oxide’s Importance

SnO doesn’t act like its cousin SnO2. The difference in oxidation state leads to different reactivity. As an amphoteric oxide, SnO reacts with both acids and bases, showing off flexibility in applications. This means chemists and manufacturing pros get more options when they work with stannous oxide, adjusting processes on the fly to meet needs. You don’t see this range in every industrial chemical.

Synthesis typically starts with tin salts or by heating metallic tin in air—but not so hot that it jumps straight to SnO2. Lab techs need to hit that sweet spot in temperature and pressure, or end up with the wrong product. Controlling this process brings better outcomes in everything from creating specialty glasses to prepping catalysts for organic reactions.

Challenges and Paths Forward

There’s more to worry about than formulas. Purity and environmental safety come into play, especially as regulations around heavy metal compounds tighten up. Tin mining and refining often disrupt land and water sources. I’ve read new reports that communities living near mines call for cleanup and stricter oversight. Chemists now look for recycling, recovery of tin, and better waste handling. Cleaner synthesis methods reduce risk without driving costs through the roof.

Education remains key—even students can mix up the oxidation states if lessons don’t emphasize why SnO and SnO2 behave so differently. Spending time with both the theory and the reality in the lab cements the difference. More hands-on learning, less rote memorization, helps create chemists and engineers who don’t just recognize a formula, but also appreciate why it matters in context.

Is Stannous Oxide safe to handle?

Understanding Stannous Oxide

Stannous oxide, also known as tin(II) oxide, often pops up in laboratories, manufacturing zones, and even a few science classrooms. As someone who has spent a fair amount of time handling different materials for research and industrial projects, I’ve learned the importance of recognizing what chemicals do and what they can mean for your health. With a powdery gray look and a history of industrial use, stannous oxide stands out as a compound that can do some good—if you treat it right.

Health Risks and Safety Concerns

On paper, stannous oxide doesn’t sound terrifying. Its toxicity rating lands on the lower side compared to strong acids or heavy metals. But “low toxicity” never means you can skip the lab gloves. Inhaling dust and letting it touch your skin can set off irritation or, with repeated exposure, set up chronic problems. Eyes and lungs especially don’t mix well with chemical powders, even seemingly mild ones.

There’s also that matter of how stannous oxide reacts around air and water. It may break down or change into other tin compounds. Some of these, like stannic oxide or tin salts, can become more reactive or harder to clean up. I remember once, in a poorly vented classroom, a handful of students learned about chemical dust the hard way—a sneezing fit and a clean-up request later, the lesson lasted longer than the lecture.

Seriousness of Proper Handling

Professional safety guidelines urge folks to use gloves, eye protection, and dust masks whenever stannous oxide is on the bench. I’ve seen the difference proper gear makes. One careless moment—sleeves rolled and no goggles—left me rinsing my eye at a station and cursing my shortcut. Even without a serious injury, the hassle wasn’t worth it.

The World Health Organization and various safety agencies don’t place stannous oxide in the same category as mercury, lead, or asbestos. Still, repeated contact, especially on job sites with little airflow or cleaning support, raises the risk of long-term effects. Simple habits like closing containers, cleaning up spills, and using extraction fans become more than formalities. Those steps determine whether people go home healthy or not.

Responsible Use in Education and Industry

Stannous oxide does a lot of work in labs—think catalysts, ceramics, or chemical synthesis. Teachers or students dealing with the powder in schools ought to lean on pre-measured solutions or pellets, where the dust risk drops. Employees in factories or processing plants must keep Material Safety Data Sheets close and review them as part of regular safety drills. It helps that regulatory bodies update their hazard and storage rules every few years. Staying current saves headaches later.

Improving safety culture means more than taping a poster to the wall. Open conversations, hands-on training, and simple reminders about why we follow protection procedures make a world of difference. Stannous oxide won’t win prizes for drama, but treating it with casual respect—matching tools, knowledge, and care—keeps everyone in the game without incident.

How should Stannous Oxide be stored?

The Risks That Shape Good Practice

Stannous oxide, or tin(II) oxide, pops up in lots of labs and factories. It gets used in ceramics, glass, and sometimes even in a chemistry classroom. This stuff doesn’t yell for attention, but it has a way of creeping into trouble if let loose. Exposure to moisture and air slowly changes its nature, turning it into a different compound. The old white powder takes on shades of yellow or brown, loses its intended use, and sometimes gives off unwanted byproducts.

I remember the first time I worked with stannous oxide. Our lab manager showed us a jar, half-full with what should have been a pure white powder. Inside sat a patchy, off-colored mess. Someone left the jar uncovered for a weekend. Nobody got hurt, but we had to toss that batch and reset our workflow. Too much humidity, and you might watch it transform into something useless.

Why Conditions Matter

Tin(II) oxide plays by the rules of science—leave it out, and it reacts with oxygen, turns to tin(IV) oxide, and there goes your carefully planned synthesis. Storing it well protects both the people handling it and the materials they work with. Keep it away from acids, since they can make stannous oxide break down and release tin ions, which aren’t always easy to remove once dispersed. For businesses focused on consistent product quality, cutting corners with how this compound is kept just invites wasted money and time.

What Proper Storage Looks Like

Sticking the jar on an open shelf doesn’t cut it. A tight-sealing container slows oxidation. Glass jars with rubber gaskets tend to work best—plastic sometimes lets in unseen air or water vapor. Many labs rely on desiccators, sometimes simple ones lined with silica gel; that extra step pays off. You’ll see the difference years down the line, when the bottle you stored last season still fits specs. Keeping it cool helps, but don’t put it in the fridge with your lunch. Room temperature in a dry spot usually makes sense, especially if the area stays close to 20 degrees Celsius.

Mark the container’s label with the date received and your initials. This habit rarely gets the credit it deserves. Track how long the powder has sat on the shelf. Some places set expiration dates, just as grocery stores do for milk. The logic is the same: old stock loses punch. By rotating supplies, labs cut down on unexpected failures.

Looking After People, Not Just Products

There’s also the safety side. Accidental spills or dust clouds can bother the lungs. Keep stannous oxide containers below face level, on sturdy shelves, and always screw the lids on right after use. A few years back, I watched a well-meaning student bump into an open jar. Dust went airborne, and suddenly, everyone in the lab reached for their masks. Accidents don’t happen as often if you develop good storage habits from the first day.

Building Long-Term Reliability

Set up a simple checklist. Look out for any moisture around the lid, off-color powder, and leaks. Don’t let the storage area fill with clutter or unrelated chemicals that might react if something spills. Keep everything labeled and dated. It’s not about rules for rules’ sake. A little discipline goes a long way in keeping both people and materials safe for the long haul.

What are the physical properties of Stannous Oxide?

A Close Look at This Inorganic Compound

Stannous oxide, known to chemists as SnO, belongs to the family of tin compounds. It stands out with a pure, blue-black or dark brown color in its stable state, a feature that surprises many who expect more from something as simple as tin and oxygen put together. Pick up a bit of it, and you'll notice a fine powder that sticks lightly to your fingertips. It’s heavier than it looks. For each cubic centimeter, you’re looking at a density of about 6.95 grams. That’s more than twice the heft you get from bricks of common glass. So in practical use, even a small volume carries noticeable weight.

Getting a Feel for Its Texture and Stability

SnO doesn’t melt the way sugar does. You need serious heat—over 1,080 degrees Celsius—before it starts thinking of turning liquid. Pop it in a furnace, and it quickly shows that stubborn streak. Below that, it clings to its form, resistant to changing shape or structure. Under everyday conditions, the compound keeps to itself, not eager to react unless provoked by strong bases or acids. Left on a shelf in a dry place, stannous oxide mostly stays out of trouble. In the open air, that's a different story. Given enough time and a whiff of moisture, the surface may scab over with tin dioxide (SnO₂), which sports a pale white color and tells another story of tin and oxygen.

Clues in the Crystal Structure

Every solid comes with its own internal order. Microscopically, SnO lines up in a tetragonal arrangement. This order gives rise to some of its heft and resilience. That structure helps in resisting pressures during storage or mixing, whether you’re handling a beaker in a research lab or scooping a sack at an industrial plant.

Conductivity: Between Metals and Insulators

People usually imagine powders like this as dead to electricity. Stannous oxide bucks that expectation by offering a bit of conductivity. Not on the same level as copper, but enough to matter in certain electronics and sensors. This makes it useful as a part of conductive ceramics and in specialty glass coatings. The balance between holding its shape and allowing electrons to pass gives SnO a small but real role in new-age devices.

Safety, Handling, and Looking Forward

Practical experience tells me to keep dust from getting airborne. The low melting point, while not extreme, calls for some care when mixing with more reactive substances. Stability breaks down at higher temperatures or strong chemical exposure, but for day-to-day work, gloves and a basic dust mask cover most safety needs. According to reliable data from the National Institute for Occupational Safety and Health (NIOSH), standard industrial hygiene effectively keeps risks in check, though basic respect for the powder must never give way to carelessness.

In every bag or flask of stannous oxide, there’s a tangle of science that keeps chemists curious. It’s not just the blue-black color or sturdy feel—it ties together fundamental concepts as well as real-world utility. With responsible handling and clear understanding of its properties, stannous oxide earns its place across research labs and factory floors, bridging old chemistry with new possibilities.

Stannous Oxide
Stannous Oxide
Stannous Oxide
Names
Preferred IUPAC name oxostannane
Other names Stannous monoxide
Tin(II) oxide
Tin monoxide
Pronunciation /ˈstæn.əs ˈɒk.saɪd/
Identifiers
CAS Number 21651-19-4
Beilstein Reference 3599806
ChEBI CHEBI:30527
ChEMBL CHEMBL1408548
ChemSpider 12717
DrugBank DB13933
ECHA InfoCard 100.028.302
EC Number 215-231-4
Gmelin Reference 778656
KEGG C18789
MeSH D013243
PubChem CID 166873
RTECS number XP7200000
UNII 1T0TJA2PMZ
UN number UN1386
CompTox Dashboard (EPA) `DTXSID5022851`
Properties
Chemical formula SnO
Molar mass 150.71 g/mol
Appearance Blue-black powder
Odor Odorless
Density 6.95 g/cm³
Solubility in water Insoluble
log P -0.26
Vapor pressure Negligible
Acidity (pKa) 6.6
Basicity (pKb) 6.8
Magnetic susceptibility (χ) '+530.0·10⁻⁶ cm³/mol'
Refractive index (nD) 2.09
Viscosity Powder/Solid
Dipole moment 3.59 D
Thermochemistry
Std molar entropy (S⦵298) 56.5 J·mol⁻¹·K⁻¹
Std enthalpy of formation (ΔfH⦵298) -285.9 kJ/mol
Std enthalpy of combustion (ΔcH⦵298) -578.0 kJ/mol
Pharmacology
ATC code A01AB55
Hazards
Main hazards Harmful if swallowed, causes skin and eye irritation
GHS labelling GHS02, GHS07
Pictograms GHS07,GHS09
Signal word Warning
Hazard statements H315, H319, H335
Precautionary statements H261; P210; P231+P232; P280; P370+P378; P402+P404; P501
NFPA 704 (fire diamond) 2-1-1
Lethal dose or concentration LD50 oral rat 700 mg/kg
LD50 (median dose) > 2,000 mg/kg (rat oral)
NIOSH SN1225000
PEL (Permissible) PEL: 2 mg/m3
REL (Recommended) 0.5 mg/m³
IDLH (Immediate danger) 100 mg/m3
Related compounds
Related compounds Tin(IV) oxide
Tin(II) chloride
Tin(IV) chloride